期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 22, 页码 7485-7493出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b01042
关键词
-
资金
- National Science Foundation [CHE-0957416, CHE-030089]
- U.S. Department of Education (GAANN fellowships)
Dynamics calculations are described for carbocation rearrangements involving product-forming pathways with post transition-state bifurcations. We show that noncovalent interactions with associated benzene rings (a simple model of aromatic amino add side chains) can switch inherent dynamical tendencies for competing modes of disrotation, establishing that meaningful changes in dynamically controlled product selectivity can be achieved with few weak noncovalent interactions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据