期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 12, 页码 4322-4325出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b01098
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资金
- Deutche Forschungsgemeinschaft [ME 1805/13-1]
A novel ruthenium catalyst is introduced which contains solely achiral ligands and acquires its chirality entirely from octahedral centrochirality. The configurationally stable catalyst is demonstrated to catalyze the alkynylation of trifluoromethyl ketones with very high enantioselectivity (up to >99% ee) at low catalyst loadings (down to 0.2 mol%).
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