期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 15, 页码 5281-5284出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b13285
关键词
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资金
- National Science Foundation [CHE-1152294]
- SAXS/ WAXS [DMR-1228957]
Spin-casting of a cellobiose-atactic poly propene (CB-aPP) conjugate (1) from a 0.1% (w/w) n-butanol/hexane solution onto highly oriented pyrolytic graphite (HOPG) and carbon-coated Si(100) spontaneously produced microphase-separated sub-10-nm nano structured ultrathin films in the form of alternating CB and aPP lamellar domains (d = 6.60 +/- 0.68 nm) that are oriented perpendicular to the substrate surface. Thermal annealing at modest temperatures (e.g., 50-100 degrees C), and as low as the physiologically relevant temperature of 38 degrees C, serves to drive a structural transition that yields a parallel stacked bilayer assembly as the thermodynamically favored nanostructure. These results establish the advantage of low molecular weight, narrow polydispersity, and amorphous, low T-g, poly(alpha-olefinate)s (xPAOs) as a new class of hydrophobic building block for amphiphilic materials, and sugar PAO conjugates in particular, for the development of stimuli-responsive, nanostructured materials for technological applications at physiological temperatures.
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