期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 39, 页码 13680-13683出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b08667
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资金
- Research Grants Council of The Hong Kong Special Administration Region [14320616, N_HKUST603/15]
- Vice-Chancellor's (CUHK) Discretionary Fund
A borylene cation stabilized by bis(silylene) and carbon monoxide was prepared and structurally characterized via the reaction of bis(silylene)-stabilized bromoborylene with W(CO)(6). This is the first example of a borylene cation coordinated by three neutral ligands, which: can be viewed as a cationic form of a king-sought Lewis, base-stabilized zerovalent boron compound. This cation can cleave dihydrogen.
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