期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 28, 页码 9467-9470出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b04838
关键词
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资金
- JST ACT-C Grant [JPMJCR12Y3]
- JSPS [24245019, 15H05800, 17H06143]
- Grants-in-Aid for Scientific Research [15H05800, 17J07437, 17H06143] Funding Source: KAKEN
A highly useful, visible-light-driven carboxylation of aryl bromides and chlorides with CO2 was realized using a combination of Pd(OAc)(2) as a carboxylation catalyst and Ir(ppy)(2)(dtbpy)(PF6) as a photoredox catalyst. This carboxylation reaction proceeded in high yields under 1 atm of CO2 with a variety of functionalized aryl bromides and chlorides without the necessity of using stoichiometric metallic reductants.
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