期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 62, 页码 9088-9091出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc04198b
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Highly volatile and valuable reagents, perfluoroiodides were shown to complex with ionic liquids with the aid of a halogen-bond between a diverse set of anions and the electrophilic iodine atoms in perfluorinated iodides. The affinity of anions in various ionic liquids towards perfluoroiodides was examined by F-19 NMR. Making use of the non-volatility of ionic liquids, we demonstrate here that perfluoroiodides can be stored and released controllably, on demand, from an ionic liquid matrix.
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