期刊
DALTON TRANSACTIONS
卷 48, 期 30, 页码 11191-11195出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt01921a
关键词
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资金
- ANR [ANR-11-INTB-1008 MENOLEP]
- CNRS
- Universite de Bourgogne
- Universite de Toulouse
- Conseil Regional de Bourgogne through the plan d'actions regional pour l'innovation (PARI-3MIM)
- Conseil Regional de Bourgogne through the plan d'actions regional pour l'innovation (PARI-CDEA)
- fonds Europeen de Developpement Regional (FEDER) programs
- Agence Nationale de la Recherche (ANR) [ANR-11-INTB-1008] Funding Source: Agence Nationale de la Recherche (ANR)
A new class of tritopic ferrocene-based ambiphilic compounds has been prepared by assembling diphosphino- and boryl-substituted cyclopentadienides at iron. The presence of five sterically demanding substituents on the ferrocene platform induces conformational constraints, as is apparent from XRD and NMR data, but does not prevent the chelating coordination to platinum. The Lewis acid moiety is pendant in both the free ligand and the platinum complex.
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