期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 31, 页码 10903-10908出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b06408
关键词
-
资金
- MEXT [JP15H05756, JP16K05694]
- ACT-C Program from JST [JPMJCR12Z9]
- JSPS
- Kyoto University Foundation
- Grants-in-Aid for Scientific Research [15H05756, 16K05694] Funding Source: KAKEN
A cationic ruthenium(II) complex catalyzes double-bond transposition of 1,1-di(boryl)alk-3-enes to generate in situ 1,1-di(boryl)alk-2-enes, which then undergo chiral phosphoric acid catalyzed allylation of aldehydes producing homoallylic alcohols with a (Z)-vinylboronate moiety. 1,2-Anti stereochemistry is installed in an enantioselective manner. The (Z)-geometry forged in the products allows their isolation in a form of 1,2-oxaborinan-3-enes, upon which further synthetic transformations are operated.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据