4.7 Article

Selective production of indane and its derivatives from lignin over a modified niobium-based catalyst

期刊

CHEMICAL COMMUNICATIONS
卷 55, 期 63, 页码 9391-9394

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc04101j

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资金

  1. NSFC of China [21872050, 21832002, 21808063]
  2. Fundamental Research Funds for the Central Universities [222201718003]
  3. Science and Technology Commission of Shanghai Municipality [18ZR1408500, 10dz2220500]
  4. Zhang jiangshu'' excellent PhD scheme of ECUST

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Starting from native lignin, the first example of the efficient production of indane and its derivatives was achieved over a CH2Cl2-modified Ru/Nb2O5 catalyst. Intensive characterization reveals that CH2Cl2 weakens the hydrogenolysis ability of Ru particles through the strong interaction between CH2Cl2 and Ru, and promotes the intramolecular cyclization reaction.

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