期刊
CRYSTENGCOMM
卷 21, 期 31, 页码 4593-4598出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ce00715f
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资金
- Fundamental Research Funds for the Central Universities [2018CDYJSY0055]
- Graduate Research and Innovation Foundation of Chongqing [CYS18002]
- National Natural Science Foundation of China [21576034]
- Joint Funds of the National Natural Science Foundation of China-Guangdong [U1801254]
- Innovative Research Team of Chongqing [CXTDG201602014]
In this work, the evolution process of delta-MnO2 from 2-D nanosheets to 1-D nanofibers has been systematically investigated by regulating the concentration of reactants, reaction time and temperature. The morphological evolution and growth process could be described by a dissolution-recrystallization mechanism. In detail, the partial nanosheets dissolve in the solution and serve as sources supplied for the growth of nanofibers, while other portions grow directly to form larger and irregular nanosheets and then re-dissolve due to the limited solubility. The conversion of delta-MnO2 from nanoflakes to nanofibers mainly depends on the concentrated NaOH solution, adequate reaction period and suitable reaction temperature in the hydrothermal reaction. Importantly, sufficient Na+ ions in solution play an important role to keep the delta phase structure. In addition, the 1-D delta-MnO2 nanofibers can be a promising candidate as supercapacitor electrode.
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