期刊
CHEMICAL SCIENCE
卷 10, 期 31, 页码 7426-7432出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9sc01824g
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资金
- CSIR, India
- IITB-Monash Research Academy
- UGC-India
- Australian Research Council [DP180103047]
- University of Queensland
Rhodium catalysis has been extensively used for ortho-C-H functionalization reactions, and successfully extended to meta-C-H functionalization. Its application to para-C-H activation remains an unmet challenge. Herein we disclose the first example of such a reaction, with the Rh-catalyzed para-C-H olefination of arenes. The use of a Si-linked cyanobiphenyl unit as a traceless directing group leads to highly para-selective arene-olefin couplings.
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