期刊
IET NANODIELECTRICS
卷 2, 期 3, 页码 103-108出版社
WILEY
DOI: 10.1049/iet-nde.2019.0010
关键词
permittivity; electric breakdown; filled polymers; nanofibres; barium compounds; ceramics; polymer fibres; electrospinning; nanofabrication; polymer films; sandwich structures; dielectric losses; nanocomposites; core-shell nanostructures; high energy storage applications; ceramic fillers; electrical technology; electronic technology; ceramic nanofibres; energy density; three-layer sandwich structure; dielectric properties; insulation layer; electrospinning method; core-shell structured nanofibres; barium titanate nanofibres; sandwich-structured poly(vinylidene fluoride-co-hexafluoropropylene) composite films; energy storage; breakdown strength; permittivity; BaTiO3; Al-2 O-3; BaTiO3 -Al-2 O-3; BaTiO3
类别
资金
- National Basic Research Program of China (973 Program) [2015CB654603]
- State Grid Corporation of China [SGRDGKJ[2017]634]
- National Nature Science Foundation of China [51622701, 51425201]
- Beijing Nova Program [Z181100006218006]
- Fundamental Research Funds for the Central Universities [FRF-TP-16-001C1]
Polymer-based composites with ceramic fillers could combine the advantages of both, which can be potentially used in electrical and electronic technology. In this work, the barium titanate (BaTiO3) nanofibres and the core-shell structured BaTiO3 @Al-2 O-3 nanofibres with Al-2 O-3 insulation layer coated on the BaTiO3 surface were both prepared via the electrospinning method. The appropriate incorporation of the ceramic nanofibres effectively improves the dielectric properties and energy density of the polymer. Moreover, the poly(vinylidene fluoride-co -hexafluoropropylene)-based composite films with the three-layer sandwich structure were fabricated to further promote the dielectric properties. The results show that the outer two layers with a higher content of BaTiO3 nanofibres can make more contribution to the improved permittivity of the composites. In addition, the introduction of the interlayer with low loading of BaTiO3 @Al-2 O-3 nanofibres promotes the breakdown strength. This work gives rise to the potential in high energy storage applications.
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