期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 7, 期 32, 页码 19045-19059出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta06852j
关键词
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资金
- self-determined research funds of CCNU from the colleges' basic research and operation of MOE [CCNU19TS038, 2019QN017]
- Wuhan Planning Project of Science and Technology [2018010401011294]
- Recruitment Program of Global Youth Experts of China
NiFe alloys and metal-nitrogen-carbon materials (M-N-C, M = Ni, Fe, Co, etc.) are foremost catalysts in the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) process, respectively. Nevertheless, the monotonic performance and insufficient stability hinder their practical application in rechargeable batteries. Herein, we simultaneously combine Ni(Fe)OOH and Ni/Fe-N-C active sites together into 3D interconnected core-shell nanochains (Ni2Fe1@PANI-KOH900). The obtained catalyst exhibits robust activity and durability in both OER and ORR reactions with a startlingly low overpotential of 240 mV at a current density of 10 mA cm(-2) (E-j=10 = 1.47 V vs. RHE) and a more positive half-wave potential (E-1/2 = 0.92 V vs. RHE), superior to those of the benchmark RuO2 and Pt/C catalysts. The potential gap (Delta E = E-j=10 - E-1/2) is merely 0.55 V. Intensive investigations through in situ confocal Raman and HTEM-HAADF techniques indicate that the Ni(Fe)OOH and Ni/Fe-N-C active species as well as the unique 3D interconnected network-like structure are responsible for the state-of-the-art OER and ORR performances. Furthermore, the assembled rechargeable Zn-air battery comprising Ni2Fe1@PANI-KOH900 exhibits unprecedented superior charging-discharging performance and durable cycle life, holding great potential for energy conversion and storage devices.
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