期刊
GREEN CHEMISTRY
卷 21, 期 16, 页码 4319-4323出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc01331h
关键词
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资金
- National Natural Science Foundation of China [21506177, 21676223]
- special fund for Fujian Ocean High-Tech Industry Development, China [FJHJF-L-2018-1]
- Natural Science Foundation of Fujian Province of China [2019J06005]
- Energy Development Foundation of the College of Energy, Xiamen University [2017NYFZ02]
- New Zealand Ministry of Business, Innovation and Employment (MBIE) [16-UOA-049-CSG]
99% yield of 2,5-dihydroxymethylfuran (DHMF) was achieved from biomass derived 5-hydroxymethylfurfural (HMF) with novel CuNPs@ZIF-8 using a relatively low hydrogen pressure and short reaction time. The activation energy of transformation of HMF to DHMF is only 39 kJ mol(-1) and the TOF value reached is 21 h(-1). The coexistence of Cu-1 and Cu-0 in Cu species is demonstrated to contribute to the high activity for the hydrogenation of HMF to DHMF.
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