4.6 Article

Locally favoured structures and dynamic length scales in a simple glass-former

出版社

IOP PUBLISHING LTD
DOI: 10.1088/1742-5468/aa4e92

关键词

dynamical heterogeneities; glasses (colloidal, polymer, etc); glasses (structural); slow relaxation; glassy dynamics; aging

资金

  1. European Research Council (ERC consolidator grant NANOPRS) [617266]
  2. Institut Universitaire de France

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We investigate the static and dynamic properties of a weakly polydisperse hard sphere system in the deeply supercooled state, i.e. at densities higher than that corresponding to the mode-coupling transition. The structural analysis reveals the emergence of icosahedral locally favoured structures, previously only found in trace quantities. We present a new approach to probe the shape of dynamically heterogeneous regions, which is insensitive to particle packing effects that can hamper such analysis. Our results indicate that the shape of the dynamically heterogeneous regions changes only weakly and moreover hint that the often-used four-point correlation length may exhibit a growth in excess of that which our method identifies. The growth of the size of the dynamically heterogeneous regions appears instead to be in line with the one of structural and dynamic propensity correlations.

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