期刊
CHEMICAL SCIENCE
卷 10, 期 33, 页码 7807-7811出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9sc02810b
关键词
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资金
- U.S. Department of Energy, Office of Science, Basic Energy Sciences, Catalysis Science Program [DE-SC0009376]
- Agence Nationale de la Recherche [ANR-16-CE07-0019-Hel-NHC]
- National Science Foundation [CHE-1455348, DGE-1650112]
The popularity of NHCs in transition metal catalysis has prompted the development of chiral versions as electron-rich neutral stereodirecting ancillary ligands for enantioselective transformations. Herein we demonstrate that cyclic (alkyl)(amino)carbene (CAAC) ligands can also engage in asymmetric transformations, thereby expanding the toolbox of available chiral carbenes.
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