期刊
JOULE
卷 3, 期 8, 页码 1937-1948出版社
CELL PRESS
DOI: 10.1016/j.joule.2019.05.020
关键词
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资金
- National Key Projects for Fundamental Research and Development of China [2018YFB1501602, 2016YFA0202801]
- National Natural Science Foundation of China [21690080, 21690084, 21673228, 21721004, 21606227]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB17020100]
- Dalian National Laboratory for Clean Energy [DNL180303]
Cellulosic ethanol is one of the most important biofuels, yet its commercial production is hindered by the low-efficiency and high-cost bioconversion process. Here, we report a new chemocatalytic approach for the one-pot production of cellulosic ethanol. With a multifunctional Mo/Pt/WOx catalyst, cellulose is directly converted to ethanol in a one-pot reaction with a yield as high as 43.2 C%. Kinetic analysis reveals that such a one-pot process involves tandem catalysis from cellulose to ethylene glycol (rapid) followed by hydrogenolysis of ethylene glycol to ethanol (slow). Characterizations show that isolated and low-coordinated MoOx bonds to metallic Pt particles on the mesoporous WOx support, constituting xOMo-PtWOx interfacial sites, which offer high activity for C-O cleavage of ethylene glycol.
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