4.6 Article

Silica functionalized Cu(II) acetylacetonate Schiff base complex: An efficient catalyst for the oxidative condensation reaction of benzyl alcohol with amines

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JOURNAL OF SOLID STATE CHEMISTRY
卷 253, 期 -, 页码 305-312

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ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2017.06.012

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Silica; Cu(Il) acetylacetonate Schiff base complex; 3-Aminopropyltriethoxysilane; Oxidative condensation

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Silica functionalized Cu(II) acetylacetonate Schiff base complex via the one pot reaction of silica functionalized 3-aminopropyltriethoxysilane with acetyl acetone and copper acetate has been reported. The synthesized material was well characterized by analytical techniques such as FT-IR, UV-DRS, XRD, SEM-EDX, HR-TEM, EPR, ICP-AES and BET analysis. The characterization results confirmed the grafting of Cu(II) Schiff base complex on the silica surface. The catalytic activity of synthesized silica functionalized Cu(II) acetylacetonate Schiff base complex was evaluated through the oxidative condensation reaction of benzyl alcohol to imine.

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