期刊
JOURNAL OF SOILS AND SEDIMENTS
卷 18, 期 6, 页码 2379-2386出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11368-017-1711-7
关键词
Compound forms; Copper; Extractant selectivity; Fractionation methods; Soils; Responsible editor: Jaume Bech
资金
- Ministry of Education and Science of Russia [5.948.2017/PP]
- RFBR [16-35-60055, 16-34-00573]
It is very important to obtain the information on the soils capacity to immobilize HMs and distribute them among soil components. The aim of this work was to study the fractional composition of Cu compounds in Haplic chernozem under model contamination conditions using different fractionation methods. The fractional composition of copper compounds in Haplic Chernozem artificially contaminated with copper acetate has been studied under model experimental conditions. General regularities and differences in the distribution of Cu forms in soils at the use of sequential fractionation by the Miller method modified by Berti and Jacobs (1996) and the Tessier method (Tessier et al. 1979) are revealed. The differences are related to the metal affinity for specific carrier phases, as well as to the selectivity and extraction capacity of the reagents used in these methods. A significant increase in the most mobile exchangeable Cu fraction is observed in contaminated soils. Aluminosilicates and soil organic matter make the largest contribution to the adsorption and retention of Cu. The Tessier method is more suitable for the separation of the total technogenic component from contaminated soils. The Miller method is more informative at the determination of loosely bound HM compounds because of the use of weaker extractants.
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