期刊
JOURNAL OF CHEMICAL SCIENCES
卷 131, 期 8, 页码 -出版社
INDIAN ACAD SCIENCES
DOI: 10.1007/s12039-019-1657-y
关键词
Bis(NHC)Pd(II) complex; butylfuran; butylthiophene; direct arylation; N-coordinate-Pd(II)(NHC) complexes; N-heterocyclic carbene
资金
- [2010.KB.FEN.13]
The direct arylation reaction has attracted attention in recent years especially because of its environment-friendly properties. In this study, we researched the synthesis of 2-hydroxyethyl substituted bis(NHC)Pd(II) complexes and also the synthesis of N-coordinate-Pd(II)(NHC) complexes containing N-bound benzimidazolium from palladium acetate ([Pd(CH3COO)(2)]) with 1,3-disubstituted benzimidazolium halides in DMSO. All the complexes have been characterized by using H-1 NMR, C-13 NMR, FTIR spectroscopy and elemental analysis techniques. The molecular and crystal structure of one of the complexes is confirmed by using single-crystal X-ray diffraction. These complexes have been examined as the catalyst in the direct arylation reaction with 2-n-butylfuran and 2-n-butylthiophene and have demonstrated excellent activity in this reaction.
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