期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 17, 期 22, 页码 5413-5419出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob00734b
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Recently, photoinduced radical difluoromethylation has emerged as a step-economical synthetic method of CHF2-containing compounds. In this article, difluoromethylation of alkenes, isonitriles and aryl bromides promoted by photoredox catalysis is described together with a non-catalytic photoinduced system. Representative reactions will be discussed for each highlighted difluoromethylating reagent. In addition, related monofluoromethylation with their corresponding monofluoromethylating reagents is also discussed.
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