期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 69, 页码 10265-10268出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc05099j
关键词
-
资金
- National Natural Science Foundation [21772046]
- Natural Science Foundation of Fujian Province [2016J01064]
A Cu-catalyzed synthesis of 1,2-thiobenzonitriles via oxidative C-N cleavage of 3-aminoindazoles followed by radical coupling with thiols is developed. A diverse array of 1,2-thiobenzonitriles were obtained in good yields with wide substrate scope. Notably, this is the first example of denitrogenative radical coupling with 3-aminoindazoles.
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