期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 70, 页码 10342-10358出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc05139b
关键词
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资金
- US Department of Energy, Office of Science, Office of Basic Energy Sciences Award [DE-SC0012150, DE-0000243266]
- Sloan Foundation
- Canadian Institute for Advanced Research (CIFAR) Azrieli Global Scholar in the Bio-Inspired Solar Energy Program
- Camille Dreyfus Teacher-Scholar
Most bond-forming and -breaking redox reactions require the concomitant transfer of protons. Unassisted proton movement can result in kinetic and thermodynamic barriers that inhibit the rate of these reactions, leading to slow and/or inefficient catalysis. These barriers can be circumvented by effective proton management through molecular design. Different strategies for managing proton movement are discussed with examples from biological and synthetic systems. As proton management is particularly important in redox reactions for chemical fuel generation and utilization, the focus will be on catalysts for H-H and O-O bond formation and cleavage. However, we expect the approaches discussed herein will be general to most multi-electron, multi-proton reactions.
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