4.5 Article

Use of Ionic liquids as additives in ion exchange chromatography for the analysis of cations

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JOURNAL OF SEPARATION SCIENCE
卷 40, 期 21, 页码 4113-4119

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/jssc.201700408

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alkali metal ions; alkaline earth metal ions; ion exchange chromatography; ionic liquids; mobile phases

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The behavior of acids (citric acid, nitric acid, oxalic acid, tartaric acid) as a mobile phase and imidazolium ionic liquids (the bromides, tetrafluoroborates and hexafluorophosphates of 1-ethyl, 1-butyl, and 1-hexyl-3-methylimidazolium) as additives in ion exchange chromatography for cations (Na+, K+, Mg2+, Ca2+) separation were studied. The results showed that nitric acid and 1-hexyl-3-methyl-imidazolium hexafluorophosphate offered the most interesting features in the separation of cations, such as lower retention time and better resolution. The selected optimal conditions were achieved by adding 0.10 mM 1-hexyl-3-methyl-imidazolium hexafluorophosphate in 4.0 mM HNO3 mobile phase for the separation of four cations with the flow rate of 0.9 mL/min at room temperature (25 degrees C). The linear regression equations of Na+, K+, Mg2+, Ca2+ were S = 4.4763c + 0.0209, S = 3.8903c - 0.0087, S = 6.3974c - 0.0173, and S = 7.601c - 0.0339 and the limits of detection of Na+, K+, Mg2+, Ca2+ were 0.296, 4.98, 0.0970, and 1.22 mu g/L, respectively. In this work, four cations in samples were successfully detected.

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