期刊
GREEN CHEMISTRY
卷 21, 期 17, 页码 4656-4661出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc01650c
关键词
-
资金
- National Natural Science Foundation [21272039]
Herein, we report a mild and environment-friendly synthesis of Z-5-alkylidene-2-oxazolidinones in neat water, using a low loading (2 mol%) of silver carbonate as a catalyst. Instead of pressurised gaseous carbon dioxide, potassium bicarbonate was used as the source of carboxyl. An interesting solvent effect and a C-N cleavage side reaction with a 6-endo-dig mechanism are also discussed.
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