期刊
DALTON TRANSACTIONS
卷 48, 期 34, 页码 12812-12816出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt01319a
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资金
- King Abdullah University of Science and Technology (KAUST)
(PNP)-P-3-Ir pincer hydride complexes were synthesized and characterized as catalysts and key intermediates in the direct hydrogenation of CO2 to formate under mild conditions. The formation of a dearomatized (PNP)-P-3*-Ir(i)-CO species was identified as a plausible key process accountable for the loss of catalytic activity in the CO2 hydrogenation.
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