期刊
DALTON TRANSACTIONS
卷 48, 期 34, 页码 12808-12811出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt02387a
关键词
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资金
- National Natural Science Foundation of China [21701184, 21876182, 91326112, 21422704]
- Natural Science Foundation of Jiangsu Province [BK20140007]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Young Thousand Talented Program in China
A unique selective crystallization strategy based on an iodate-sulfate mixed-anion system has been developed for lanthanide separation. Periodic divergences in crystal formation energy enable simple Nd/Dy, La/Lu, Gd/Tb, La/Dy, and Nd/Lu separations through crystallization of the early lanthanides, giving rise to separation factors up to 123(5), 100(2), 2.4(2), 137(9), and 85(6), respectively.
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