4.6 Article

Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation

期刊

RSC ADVANCES
卷 9, 期 46, 页码 26542-26546

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ra05947d

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  1. NSERC of Canada
  2. CFI
  3. RDC-NL
  4. Vanier Canada Graduate Scholarship
  5. Memorial University

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Triphenylborane catalyzes the copolymerization and terpolymerization of epoxides and CO2 to yield polycarbonates with excellent dispersity. Via assisted tandem catalysis, these materials could be hydrosilylated in a one-pot fashion yielding modified polymeric materials. Using only a few reagents, materials with glass transition temperatures ranging from 37-110 degrees C were obtained.

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