期刊
RSC ADVANCES
卷 9, 期 46, 页码 27021-27031出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ra06005g
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资金
- Department of Pharmaceuticals, the Ministry of Chemicals and Fertilizers Govt. of India, New Delhi
A novel strategy towards the synthesis of 1,4-disubstituted 1,2,3-triazoles via C-N and N-N bond formation has been demonstrated under transition metal-free and azide-free conditions. These 1,2,3-triazoles were obtained in a regioselective manner from commercially available anilines, aryl alkenes/aryl alkynes and N-tosylhydrazines using I-2 under O-2 atmosphere. Broad substrate scope, milder reaction conditions, good to moderate yields and clean protocol are the notable features of the method. Moreover, this protocol is amenable for the generation of a library of medicinally important key building blocks.
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