期刊
NANOSCALE
卷 11, 期 34, 页码 15739-15762出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9nr05107d
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资金
- National Science Foundation of China (NSFC) [51834009, 51801151, 51471132]
- Hundred Talent Program of Shaanxi Province
- Key Laboratory Project of Shaanxi Education Department [18JS070, 18JK0560, 17JS081]
- Shaanxi Province Science Fund for Distinguished Young Scholars [2018JC-027]
- China Postdoctoral Science Foundation [2018M633643XB]
- Key Research and Development Project of Shaanxi Province [2017ZDXM-GY-033, 2017ZDXM-GY-028]
- Key Laboratory Project of Science and Technology Agency [13JS075]
Exposed high-index facets with a high density of low-coordinated atoms (including edges, steps and kinks) can provide more high-active sites for chemical reactions. Therefore, great progress has made in the facet-dependent application of various high-index faceted micro-/nanostructures in the past decades. Previous review papers have mainly highlighted the advances in high-index faceted noble metal nanocrystals. However, to date, there is no specialized review paper on high-index faceted metal oxides and their facet-dependent applications. Thus, in this review, the existing high-index faceted metal oxide micro-/nanostructures, including Cu2O, TiO2, Fe2O3, ZnO, SnO2 and BiVO4, are reviewed based on their characterization, synthesis engineering and facet-dependent applications in the fields of catalysis, sensors, lithium-ion batteries and carbon monoxide oxidation. Also, several challenges and perspectives are presented. Hopefully, this review article will be a useful guideline and resource for researchers currently concentrating on high-index faceted metal oxides to design and synthesize novel micro-/nanostructures for overcoming the practical environment-, biology- and energy-related problems.
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