期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 71, 页码 10539-10542出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc05749h
关键词
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资金
- EPSRC [GR: EP/R013799/1]
- Chinese Scholarship Council (CSC)
- EPSRC [EP/R013799/1] Funding Source: UKRI
The syntheses of substituted all-cis-1,2,3-trifluorocyclopropanes are described for the first time. The three fluorines located on each of the cyclopropyl carbons with a stereochemistry where they are all on the same face of the cyclopropane, imparts a significant polarity to the molecule, and the inherent conformational rigidity and lowering of log P makes this motif attractive for exploration as a substituent for pharmaceuticals and agrochemicals research.
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