期刊
JOURNAL OF RARE EARTHS
卷 35, 期 2, 页码 177-186出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S1002-0721(17)60897-4
关键词
ion-imprinted polymers; rare earths; separation; adsorption; lanthanide-ions
资金
- Ministry of Science, Technology and Innovation, Malaysia [RDU130505, SBK0260-ST-2016]
Lanthanide-ion imprinted polymers (L-IIPs) were synthesized by stoichiometric amounts of rare earth ions and the cavities in the polymers were created for the corresponding lanthanide ions. The maximum sorption capacities were estimated to be 125.3, 126.5, 127.6, 128.2 and 129.1 mg/g for Pr, Nd, Sm, Eu and Gd, respectively at pH 6. In the selectivity study, the L-IIPs exhibited good selectivity to the specific rare earth ions in the presence of coexisting cations. The imprinting results were found to be excellent with some rare earth ions over other competitor rare earth ions with the same charges and close ionic radius.
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