期刊
ENERGY STORAGE MATERIALS
卷 21, 期 -, 页码 97-106出版社
ELSEVIER
DOI: 10.1016/j.ensm.2018.10.019
关键词
Hierarchical mesoporous structure; Heterostructure; MoSe2@CoSe/N-C; Sodium-ion batteries; Hydrogen evolution reaction
资金
- National Natural Science Foundation of China [51872334, 51572299]
- Program for New Century Excellent Talents in University [NCET-13-0594]
- Innovation-Driven Program of Central South University [2017CX001]
MoSe2 has been attracting numerous attentions for energy storage and conversion applications due to its unique characteristics. However, the intrinsic low electric conductivity and sluggish reaction kinetics hinder its electrochemical performance. Herein, hierarchical mesoporous MoSe2@CoSe/N-doped carbon (N-C) composite was in situ fabricated from MoO3@Co-MOF precursor in selenium atmosphere. The incorporation of CoSe and N-C greatly enhanced the reaction kinetics and electronic conductivity of the composite. Moreover, the hierarchical mesoporous structure ensures fast Na+ diffusion and excellent structural stability upon cycling. As expected, the optimally structured composite showed superior electrochemical performance as an anode material in sodium-ion batteries, including a high specific capacity of 485 mA h g(-1) at 0.1 A g(-1) and good rate capability that it retains 91.4% of its 398 mA h g(-1) initial capacity after 300 cycles at 2 A g(-1). When paired with Na3V2(PO4)(3)/C, it also delivers a high reversible capacity of 345 mA h g(-1) in full-cell configuration. In addition, as a catalyst, it also exhibits outstanding HER activity with a small overpotential of 64 mV and a Tafel slope of 53 mV dec(-1).
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