期刊
ENERGY STORAGE MATERIALS
卷 21, 期 -, 页码 474-480出版社
ELSEVIER
DOI: 10.1016/j.ensm.2019.06.022
关键词
High coulombic efficiency; Cathode electrolyte interface; Solid electrolyte interface; Li-S batteries; Li metal
资金
- Office of Vehicle Technologies of the U.S. Department of Energy through the Advanced Battery Materials Research (BMR) Program (Battery500 Consortium) [DE-EE0007764]
- National Science Foundation [ECCS-1542148, CHE-1338173]
A high-concentration, ether-based electrolyte with LiTFSI and LiNO3 as the co-salts is proposed, which enables stable cycling of a lithium metal battery using sulfurized polyacrylonitrile (SPAN) as the cathode material. In addition to providing excellent protection for lithium metal anodes by forming the solid electrolyte interface (SEI), the electrolyte promotes the formation of a crystalline cathode electrolyte interface (CEI) on the SPAN surface composed of LiF and LiNO2. The CEI effectively prevents the formation of soluble polysulfide species and enables stable cycling of the Li-SPAN battery. The benefit of having effective CEI and SEI layers is also demonstrated in Li-SPAN cells with limited lithium supply, which exhibit lithium cycling efficiency values consistent with or exceeding Li/Cu test results, reaching 99.5%. The development of electrolyte chemistries to enable the formation of effective CEI layers is a promising approach to long-life lithium metal batteries.
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