期刊
JOURNAL OF POWER SOURCES
卷 341, 期 -, 页码 192-198出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2016.11.008
关键词
Protonic ceramic fuel cells; Cathode materials; Ruddlesden-popper; Infiltration
资金
- National Natural Science Foundation of China [51402266, 21401171]
- College Students Innovation and Entrepreneurship Project [201410491028]
- Fundamental Research Funds for the Central Universities, China University of Geosciences (Wuhan) [CUG140608]
A Ruddlesden Popper oxide (Pr0.9La0.1)(2)(Ni0.74Cu0.21Nb0.05)O4+delta (PLNCN)-infiltratedBaZr(0.1)Ce(0.7)Y(0.2)O(3-delta) (BZCY) is developed as an electrode for protonic ceramic fuel cells (PCFCs). PLNCN nanoparticles are evenly dispersed on the surface of BZCY skeleton by using the infiltration technology. The electrochemical behavior of the PLNCN-infiltrated BZCY electrodes are evaluated in terms of infiltration loading and temperature. The impedance results of symmetric cells suggest that the optimized loading of PLNCN is approximately 46.1 wt%. Power density of the single cell as high as 0.77 W cm(-2) is achieved at 700 degrees C by using the 43.6 wt% PLNCN-infiltrated BZCY cathode, and the cell could be operated without degradation at 600 degrees C for 200 h; this finding indicates a promising alternative cathode for PCFCs. (C) 2016 Elsevier B.V. All rights reserved.
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