期刊
JOURNAL OF POROUS MATERIALS
卷 25, 期 1, 页码 63-73出版社
SPRINGER
DOI: 10.1007/s10934-017-0421-2
关键词
AlSBA-15; Various Si/Al ratio; Ionic liquid; Cumene cracking; Esterification reaction
Significant enhancement in the performance of incorporation of high content of aluminum within hierarchical mesoporous SBA-15 has been achieved by direct route using urea tetrachloroaluminate ionic liquid as novel aluminum source. The fabricated materials were fully characterized by N-2 sorption isotherms, powder X-ray diffraction (XRD), FT-IR, Al-27 MAS NMR, XRF, HRTEM and FESEM. The acidic properties of these materials have been examined using NH3-TPD. The catalytic performance was investigated using cumene cracking and the esterification reaction as a probe molecules to estimate the acidity of the material. It is worth noting that the ionic liquid with accomplished Al-O-Si bonds is an efficient precursor to synthesis AlSBA-15 with high aluminum content (nSi/mAl = 7) without destroying the structural order of the material in acidic medium. Al-27 MAS NMR spectra of AlSBA-15 show that all aluminum species were incorporated into the SBA-15 framework with nSi/mAl ratio up to 7. Overall, this work emphasize that the AlSBA-15 materials contain Bronsted and Lewis acid sites with medium acidity which makes them adequate to be adopted as acid catalysts in heterogeneous catalysis.
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