期刊
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
卷 56, 期 6, 页码 532-542出版社
WILEY
DOI: 10.1002/polb.24562
关键词
dimer; excimer; excitonic coupling; film formation; low-bandgap polymers; phase transition; self-assembly; solar cells; thin films
资金
- Hanns-Seidel-Stiftung from the German Federal Ministry of Education and Research (BMBF)
- German Science Foundation (DFG) through the Research Training Group [GRK 1640]
- State of Bavaria through the Research Network Solar Technologies go Hybrid
- State of Bavaria through the Energy Valley Bavaria
- TUM ICER project
- Marie Skodowska-Curie Actions Innovative Training Networks [H2020-MSCA-ITN-2014 INFORM - 675867]
Aggregates - that is short-ranged ordered moieties in the solid-state of -conjugated polymers - play an important role in the photophysics and performance of various optoelectronic devices. We have previously shown that many polymers change from a disordered to a more ordered conformation when cooling a solution below a characteristic critical temperature Tc. Using in situ time-resolved absorption spectroscopy on the prototypical semiconducting polymers P3HT, PFO, PCPDTBT, and PCE11 (PffBT4T-2OD), we show that spin-coating at a temperature below Tc can enhance the formation of aggregates with strong intra-chain coupling. An analysis of their time-resolved spectra indicates that the formation of nuclei in the initial stages of film formation for substrates held below Tc seems responsible for this. We observe that the growth rate of the aggregates is thermally activated with an energy of 310 meV, which is much more than that of the solvent viscosity (100 meV). From this we conclude that the rate controlling step is the planarization of a chain that is associated with its attachment to a nucleation center. The success of our approach for the rather dynamic deposition method of spin-coating holds promise for other solution-based deposition methods. (c) 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018, 56, 532-542
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