期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 74, 页码 11115-11118出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03612a
关键词
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资金
- National NSFC [21702106]
- Natural Science Foundation of Jiangsu Province [BK20170967]
- Nanjing Tech University [39839101, 39837101]
Ruthenium-catalyzed heteroannulation between enamides and isocyanates has been realized as a complementary approach to conventional strategies for the synthesis of pyrimidin-4-ones. High step- and atom-economy was achieved for the rapid construction of such privileged scaffolds, which are found in a multitude of pharmaceutical compounds. The generality and practicability of this transformation were reflected by the broad scope of substrates with diverse functional groups, large-scale synthesis, and late-stage diversification.
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