期刊
GREEN CHEMISTRY
卷 21, 期 18, 页码 4976-4980出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc02665g
关键词
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资金
- National Natural Science Foundation of China [21520102003]
- Hubei Province Natural Science Foundation of China [2017CFA010]
- Program of Introducing Talents of Discipline to Universities of China (111 Program)
The tandem cyclization of olefinic carbonyls with easily accessible diselenides facilitated by electrochemical oxidation has been successfully developed, which provides an environmentally friendly method for the construction of C-Se and C-O bonds simultaneously. A series of seleno dihydrofurans and seleno oxazolines, bearing fragile heterocycles, subtle C-I bonds and supernumerary vinyl groups, were forged using this elegant chelation strategy. Neither metal catalysts nor external chemical oxidants are required to promote this transformation.
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