期刊
CHINESE JOURNAL OF ORGANIC CHEMISTRY
卷 39, 期 8, 页码 2226-2234出版社
SCIENCE PRESS
DOI: 10.6023/cjoc201903040
关键词
cyclization; cycloalcohol; 1,3-dicarbonyl compound; dihydrofuran
资金
- National Natural Science Foundation of China [21831002]
- Ten Thousand Talents Program
A novel method of copper-catalyzed cyclization of 1-aryl-1-cycloalcohols and 1,3-dicarbonyl compounds has been developed, affording various cycloalkane-fused dihydrofurans in moderate to excellent yields. This transformation proceeds under mild conditions and with a good tolerance of functional groups. The mechanistic investigation revealed that the reaction involved radical intermediates.
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