期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 121, 期 44, 页码 24463-24469出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.7b08429
关键词
-
资金
- Ministry of Science and Technology of Taiwan [MOST 104-2113-M-003-006-MY2, MOST 106-2113-M-029-006-MY2, MOST 106-2632-M-029-001]
- Tunghai University
In this work, both advantages of sodium-ion batteries and dual-ion batteries have been combined in an innovated sodium-ion-based dual-ion battery (SDI) system using a Na metal film as anode and a freestanding meso-carbon microbead film (FS-MCMB) as cathode. FS-MCMB in SDI battery exhibited a superior working performance with the specific capacity of 83.6 mAh/g and a remarkable long-term stability over 300 cycles. The SDI battery with FS-MCMB exhibited an advantage of high mass density loading in the range of 27.5 mg cm(-2), which was equal to a comparable capacity of 7883 mAh/g. The electrochemical impedance analysis indicated that FS-MCMB provided a superior permeability, resulting in facilitating electrolyte infiltration into MCMB structure. In-situ XRD and ex-situ Raman spectroscopy were utilized to characterize the intercalating/deintercalating process of PF6 anions into/out of MCMB during charging/discharging processes. Finally, theoretical calculations further confirmed the structural arrangement of PF6 anions in the graphite layers.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据