Fast MAS 1H NMR Study of Water Adsorption and Dissociation on the (100) Surface of Ceria Nanocubes: A Fully Hydroxylated, Hydrophobic Ceria Surface

H-1 nuclear magnetic resonance (NMR) spectroscopy was used to study hydroxylic surface species on ceria nanocubes, a crystalline, high-surface-area CeO2 that presents mostly (100) facets. Water adsorption and desorption experiments in combination with-fast magic angle spinning (MAS, 20-40 kHz) H-1 NMR provide high-resolution H-1 spectra, that allow the observation of ten resonance bands (water or hydroxyl) on or under the (100) surface. Assignments were made using a combination of adsorption and temperature-programmed desorption, quantitative spin counting, deuterium exchange, spin lattice (T-1) and spin spin (T-2) relaxation, and DFT calculations. In air, the (100) surface exists as a fully hydroxylated surface. Water adsorption and dissociation on dry ceria surfaces occur first at oxygen vacancies, but Ce3+ centers are not required since water dissociation is barrier-less on the fully oxidized surface. Surface -OH functionality occurs in two resolved bands representing isolated -OH (1 ppm) and hydrogen-bonded -OH (9 ppm), the latter being dominant. Deuterium exchange of surface hydroxyls with D2O does not occur under mild or forcing conditions. Despite large differences in the T-1 of surface hydroxyls and physisorbed water, surface hydroxyl T-1 values are independent of the presence or absence of physisorbed water, demonstrating that the protons within these two functional group pools are not in intimate contact. These observations show that, once hydroxylated, the surface -OH functionality preferentially forms hydrogen bonds with surface lattice oxygen, i.e., the hydroxylated (100) surface of ceria is hydrophobic. Near this surface it is energetically more favorable for physisorbed water to hydrogen bond to itself rather than to the surface. DFT calculations support this notion. Impurity Na+ remaining in incompletely washed ceria nanocubes increases the surface hydrophilicity. Sharp, low-field resonances observed in spectra of noncalcined nanocubes arise from kinetically trapped subsurface -OH.