期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 17, 期 37, 页码 8546-8550出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob01752f
关键词
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资金
- CNRS
- Ministere de l'Enseignement Superieur et de la Recherche
- French National Research Agency [ANR-11-LABX-0039]
- Agence Nationale de la Recherche (ANR) [ANR-11-LABX-0039] Funding Source: Agence Nationale de la Recherche (ANR)
The reductive carboxylation of aryl halides has been investigated using a samarium electrode as a sacrificial anode to yield the corresponding benzoic acids, providing a smooth strategy for CO2 activation. Carboxylation occurred after an efficient reduction of carbon dioxide mediated by an electrogenerated Sm(ii)-complex acting as a strong monoelectronic reductive reagent.
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