期刊
CHEMICAL SCIENCE
卷 10, 期 37, 页码 8527-8532出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9sc03247a
关键词
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资金
- German-Israeli Foundation
- NSERC
We report the first pi-conjugated macrocyclic system with an oligofuran backbone. The calculated HOMO-LUMO gap is similar to that of the corresponding linear polymer, indicating a remarkable electron delocalization. The X-ray structure reveals a planar conformation, in contrast to the twisted conformation of macrocyclic oligothiophenes. The intermolecular pi-pi stacking distance is extremely small (3.17 angstrom), indicating very strong interactions. The macrocycle forms large pi-aggregates in solution and shows a tendency toward highly ordered multilayer adsorption at the solid-liquid interface. The face-on orientation of molecules explains the higher hole mobility observed in the out-of-plane direction.
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