期刊
ANALYTICAL METHODS
卷 11, 期 37, 页码 4829-4834出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ay01599j
关键词
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资金
- Guangxi Natural Science Foundation of China [2018GXNSFAA138089]
- Central Public-interest Scientific Institution Basal Research Fund for the Chinese Academy of Tropical Agricultural Sciences [1630082017002, 1630082017001]
- High Level Innovation Teams of Guangxi Colleges & Universities/Outstanding Scholars Program [Guijiaoren[2018]35]
- Guangxi Preservation and Deep Processing Research in Fruit and Vegetables Talent Highland Project
- Special Fund for Distinguished Experts in Guangxi
Despite the advantages of colorimetric detection methods, their application to glucose detection in fruit and vegetable samples has been limited by interference from other matrix components. Herein, a colorimetric sensor for hydrogen peroxide and glucose detection was developed based on an enzymatic-like reaction that induced the iodine-mediated etching of gold nanoparticles (AuNPs). The AuNPs were fabricated using a MoO3-nanosheet-assisted photochemical process without any surface modification or purification steps. Furthermore, the MoO3 nanosheet residues and Mo(vi) ions leached during AuNP preparation acted directly as peroxidase-like catalysts to promote the reduction of iodate to iodine in the presence of hydrogen peroxide (or the glucose-glucose oxidase enzymatic system). The generated iodine then etched the AuNPs, resulting in an obvious colour change of the reaction solution that allowed the selective and quantitative spectrophotometric determination of hydrogen peroxide and glucose. The linear ranges for the detection of hydrogen peroxide and glucose were 40-380 mu M (R-2 = 0.99) and 100-1000 mu M (R-2 = 0.98), respectively, with detection limits of 0.55 mu M and 0.45 mu M, respectively. The developed colorimetric method was applied to the determination of glucose in water chestnuts with good recoveries (100-108%), demonstrating its applicability to glucose detection in fruits.
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