SEI Dynamics in Metal Oxide Conversion Electrodes of Li-Ion Batteries

We examine the formation of the solid electrolyte interface (SEI) on anodes made of carbon encapsulated zinc ferrite (ZnFe2O4) nanoparticles (80 nm ZFO-C) as a standard metal oxide electrode prototype. The SEI formation and phase evolution are studied by two soft X-ray absorption techniques with different probing depths in the 10-100 run range and by surface-sensitive X-ray photoemission spectroscopy at several specific capacities of the ZFO-C anodes. These techniques are shown to be able to provide information about the nature and extension of the individual chemical species within the SEI with a typical spatial resolution of 1-5 nm. A peculiar footprint of the interphase formations is obtained by comparing the chemical history of the reactive element sites in the anodes. The progressive development of the SEI in the first cycle and the variety of compositional transformations prior to stabilization are elucidated. Formation of a reversible alkyl carbonate layer, with maximum thickness of 7 nm, is detected at the SEI topmost region. On the basis of these results, we have obtained a map of suitable spatial resolution of the evolution of the different components of the interface layer.