期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 78, 页码 11711-11714出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc05783h
关键词
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资金
- Science and Engineering Research Board (SERB), India [CRG/2018/000287, EMR/2014/000013]
- CSIR, India
The hydroboration of alkenes and alkynes using easily accessible lithium compounds [2,6-di-tert-butyl phenolatelithium (1a) and 1,1 ' dilithioferrocene (1b)] has been achieved with good yields, high functional group tolerance and excellent chemoselectivity. Deuterium-labeling experiments confirm the cis-addition of pinacolborane. The methodology has been further extended to myrcene, which undergoes selective 4,3-hydroboration. DFT calculations provide insights into the mechanism.
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