期刊
JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS
卷 144, 期 -, 页码 59-89出版社
ELSEVIER
DOI: 10.1016/j.jpba.2017.02.037
关键词
Plant and fungi metabolites; Chiral natural products; Absolute configuration; Advanced Mosher's method; Biological activity
资金
- University di Napoli Federico II
- University della Basilicata
- Compagnia di San Paolo (Italy)
The review deals with the application of the NMR advanced Mosher's method for the assignment of the absolute configuration to plant and fungal metabolites belonging to different classes of natural compounds. The structural and stereochemical characterization of these naturally occurring metabolites, as well as their biological properties as possible drugs or agrochemicals is reviewed. The importance of the absolute and relative stereochemistry on their biological properties is also highlighted. Successes and failures of application of the advanced Mosher's method are reported. (C) 2017 Elsevier B.V. All rights reserved.
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