期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 7, 期 38, 页码 11919-11925出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9tc03265g
关键词
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资金
- Foundation of the Natural Science Foundation of China [21771077, 21771084, 21621001]
- National Key Research and Development Program of China [2016YFB0701100]
- 111 Project [B17020]
Covalent organic frameworks (COFs) have shown great potential for use in ion sensing; however, applications of existing COFs are limited to sensing either cations or anions. In this study, a three-dimensional COF, COF-TT, is constructed by reacting the bis(tetraoxacalix[2]arene[2]triazine) core with tetra(p-aminophenyl)methane to provide a luminescent sensor. COF-TT exhibits ultrahigh thermal stability and exceptional chemical stability in aqueous solutions over a broad pH range from 2 to 14, which signifies immense practical potential for sensing applications. Excellent selectivity and high sensitivity of COF-TT toward Fe3+ cations and CrO42-, Cr2O72-, and MnO4- anions are evident via luminescence quenching. COF-TT also exhibits excellent recyclability in terms of washing and re-exposure cycles. Both experimental data and theoretical calculations are employed to unveil the mechanisms of the quenching effect and sensing properties of COF-TT.
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