期刊
GREEN CHEMISTRY
卷 21, 期 20, 页码 5665-5670出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc00783k
关键词
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资金
- European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013) [608490]
The ability to produce large scale quantities of MOF materials is essential for the commercialisation of these frameworks to continue. Herein we report how the production of ZIF-94 can be improved from a similar to 1 g laboratory preparation to a scalable procedure allowing for large scale production of the desired framework. The synthesis of ZIF-94 was completed at room temperature, atmospheric pressure and without the use of DMF as a solvent. This method offers improvements over the current literature synthesis routes and affords a product at 18 wt% solids. To demonstrate the robustness of the derived methodology a 60 g, large scale, batch of this framework was produced which possessed a surface area of 468 m(2) g(-1). This large scale sample has superior CO2 uptake of 3.3 mmol g(-1) at 1 bar, an improvement of 30% over literature reports.
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